The color wheel, showing the primary colors in their warm and cold shades, along with their mixes.

As you see above, all three primary colors have a cold shade and a warm shade. Avoid mixing warm colors with cold ones so that your color remains pure. Cold plus cold equals cold, and vise versa.
Each color ususaly has a small amount of biased color, meaning it contains another color in it. Understanding what bias is in each color helps you make a correct mix, therefore not obtaining dirty color.
A good rule of thumb would be to avoid mixing three primary colors, EX cold red(Alizarin Crimson) containing blue, mixed with cold blue(Ultramarine Blue) containing red would give you a pure purple. On the other hand, mixing cold red(Alizarin Crimson) containing blue with warm blue(Phtalocyanine Blue) containing yellow would mean a dirty color for you have mixed three primary colors: yellow, red, and blue.
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